Ion microprobe analysis of oxygen isotope ratios in granulite facies magnetites: diffusive exchange as a guide to cooling history

Ion microprobe analysis of magnetites from the Adirondack Mountains, NY, yields oxygen isotope ratios with spatial resolution of 2–8 m and precision in the range of 1 (1 sigma). These analyses represent 11 orders of magnitude reduction in sample size compared to conventional analyses on this material and they are the first report of routinely reproducible precision in the 1 per mil range for analysis of ¹⁸O at this scale. High precision micro-analyses of this sort will permit wide-ranging new applications in stable isotope geochemistry. The analyzed magnetites form nearly spherical grains in a calcite matrix with diopside and monticellite. Textures are characteristic of granulite facies marbles and show no evidence for retrograde recrystallization of magnetite. Magnetites are near to Fe₃O₄ in composition, and optically and chemically homogeneous. A combination of ion probe plus conventional BrF₅ analysis shows that individual grains are homogeneous with ¹⁸O=8.9±1 SMOW from the core to near the rim of 0.1–1.2 mm diameter grains. Depth profiling into crystal growth faces of magnetites shows that rims are 9 depleted in ¹⁸O. These low ¹⁸O values increase in smooth gradients across the outer 10 m of magnetite rims in contact with calcite. These are the sharpest intracrystalline gradients measured to date in geological materials. This discovery is confirmed by bulk analysis of 150–350 m diameter magnetites which average 1.2 lower in ¹⁸O than coarse magnetites due to low ¹⁸O rims. Conventional analysis of coexisting calcite yields °¹⁸O=18.19, suggesting that bulk ¹⁸O (Cc-Mt)=9.3 and yielding an apparent equilibration temperature of 525° C, over 200° C below the temperature of regional metamorphism. Consideration of experimental diffusion data and grain size distribution for magnetite and calcite suggests two contrasting cooling histories. The data for oxygen in calcite under hydrothermal conditions at high P(H₂O) indicates that diffusion is faster in magnetite and modelling of the low ¹⁸O rims on magnetite would suggest that the Adirondacks experienced slow cooling after Grenville metamorphism, followed by a brief period of rapid cooling, possibly related to uplift. Conversely, the data for calcite at low P(H₂O) show slower oxygen diffusion than in magnetite. Modelling based on these data is consistent with geochronology that shows slow cooling through the blocking temperature of both minerals, suggesting that the low ¹⁸O rims form by exchange with late, low temperature fluids similar to those that infiltrated the rock to serpentinize monticellite and which infiltrated adjacent anorthosite to form late calcite veinlets. In either case, the ion microprobe results indicate that two distinct events are recorded in the post-metamorphic exchange history of these magnetites. Recognition of these events is only possible through microanalysis and has important implications for geothermometry.     

The demographic responses to famine: The case of China 1958–61

Pre-1949 China was The Sick Man of Asia, The Land of Famine. In 1949 Mao brought the communists to power and in the re-ordered world, all such problems were supposedly overcome — but not so. Thirty years ago China suffered one of the world's worst famines. Over the four years 1958–61, China suffered some 25–30 million more deaths and experienced some 30–35 million fewer births than might have been expected under normal conditions. Yet for almost a quarter of a century there would be few, outside of China, who were aware of the existence let alone the dimensions of the disaster. Access to Chinese census data since the mid-1980s has permitted a preliminary analysis of the demographic impact of the famine.Abbreviations JPRS-CEA-81-128 Joint Publications Research Service, China Economic Affairs Report 128, 1981 - JPRS-CPS-85-028 Joint Publications Research Service. China Report, Political, Sociological & Military Affairs 28, 1985     

TL dating of loess in China

TL ages of 56 loess samples collected from Xinjiang and the middle reaches of the Yellow River were determined by using fine-grained quartz and man-made light source bleaching techniques.The results indicate that :1.The well-preserved loess sections in Xinjiang began depositing 400000 a ago.The loess/paleosol series may be comparable with that observed in the middle reaches of the Yellow River but the depositing time was probably delayed by 30000-50000a.2.The bottom boundary age of the Malan loess varies from one place to another.The TL dates can be divided into two group:70000-130000 a and 30000-50000 a.The TL data are con-sistent with the appearance of two warmer climate periods since the Pleistocene,indicating obvious regional differences in stratigraphic development of loess,i.e.,paleosol occurred in the warm climate period in the same location,but loess was deposited in other locations.The initial age of loess deposition tends to become older from west to east and from south to north .In contrast ,the cold cli-matic belt showed an opposite trend.The TL ages of loess provide strong evidence for the Quaternary stratigraphy throughout geological times and the shift tendency of climatic belt.3.The depositing rate of the Malan loess along the middle reaches of the Yellow River varies from place to place but the TL age shows a linear relationship with the depositing thickness.The de-positing rate of loess in the north is higher than that in the south,suggesting that loess materials are derived from desert areas of northern China.     

Neutrino mass,luminosity variation,and spectrum of SN1987A

In this paper, the neutrino mass has been determined from SN1987a observation in a manner that the simultaneity of neutrino emission is not regarded as the starting point, but is itself defined through the analysis by Monte-Carlo simulation. The result is that the neutrino mass lies in 3–4 eV, possiblym _v 3.6 eV. Neutrino luminosity variation and neutrino spectrum are also obtained. Comparison with theories gives further support to the mass determination, and also predicts the mass of progenitor star of SN1987a to be in the range of 12–25M .The project supported by the National Natural Science Foundation of China.     

Stable carbon-isotopic compositions of lipids isolated from the ammonia-oxidizing chemoautotroph Nitrosomonas europaea

For the ammonia-oxidizing bacterium Nitrosomonas europaea, grown autotrophically using semicontinuous culturing, average biomass was depleted in ¹³C relative to CO₂ dissolved in the medium by ca. 20‰ and the total-lipid extract was depleted in ¹³C relative to biomass by 3.7‰. The n-alkyl lipids (weighted average of fatty acids) and isoprenoid lipids (weighted average of hopanoids) were both depleted in ¹³C relative to biomass by about 9‰. The large depletion in the isoprenoid lipids seems to indicate that isotopic fractionations associated with the biosynthesis of methylerythritol phosphate (MEP) affected at least two carbon positions in each isoprene unit. Among the fatty acids, trans-9-hexadecenoic acid was most depleted (13.0‰ relative to biomass), followed by cis-9- hexadecenoic acid (9.6‰) and hexadecanoic acid (6.9‰). Isotopic relationships between the three acids suggest that significant isotope effects were associated with the desaturation and cis to trans isomerization of fatty acids. Given these observations, hopanoids produced by ammonia-oxidizing bacteria growing in natural waters are likely to be depleted in ¹³C by 26–30‰ relative to dissolved CO₂. Since CO₂ at aquatic oxyclines is often depleted in ¹³C, the range of δ values expected for hopanoids is ca. −34‰ to −55‰. The δ values of geohopanoids observed in numerous studies and attributed to unspecified chemoautotrophs fall within this range.     

The bituminous mixtures of Tall-e Abu Chizan: A Vth millennium BC settlement in southwestern Iran

Various bituminous artifacts were excavated from the Tall-e Abu Chizan, a late prehistoric (Middle Susiana to Middle Uruk) settlement on the middle of the Curvy plain, between the Karun River and the Ram Hormoz Plain. All samples dated from the Vth millennium BC and cover three periods: 5000–4700 BC (Late Middle Susiana), 4700–4200 BC (Late Susiana 1) and 4200–3900 BC (Late Susiana 2). The bitumens were studied using the techniques of petroleum geochemistry and were compared both to the unaltered crude oils produced from the main oil fields in the area and to the famous Mamatain oil seeps. All samples are very rich in bitumen (average 46 wt%) which has been biodegraded and oxidized. Despite these alteration phenomena, δ¹³C of asphaltenes occur within a narrow range of less than 1‰ PDB. Biodegradation affected the steranes, terpanes, dibenzothiophenes and mono- and triaromatic steroids. Molecular characteristics of terpanes, especially the occurrence of 18α (H)-oleanane, suggest that the bitumen from Tall-e Abu Chizan is a mixture generated from Cretaceous Kazdhumi and Eocene Pabdeh petroleum source rocks. In that respect, bitumens from Tall-e Abu Chizan belong to the same oil family as oil from the Naft Safid field, which is in the vicinity of the archaeological site. In fact, the bitumen at Tall-e Abu Chizan likely originated from oil seepages at Naft Safid. These oil seeps have not yet been sampled or analysed.     

The palaeoenvironment associated with a partial Iguanodon skeleton from the Upper Weald Clay (Barremian, Early Cretaceous) at Smokejacks Brickworks (Ockley, Surrey, UK), based on palynomorphs and ostracods

In 2001 a partial skeleton of an Iguanodon was discovered in the Upper Weald Clay (Barremian, Early Cretaceous) at Smokejacks Brickworks near Ockley, Surrey, UK. When the dinosaur was excavated, a detailed stratigraphic section was logged and 25 samples taken for palynological and micropalaeontological (ostracod and megaspore) analysis, including a detailed sample set of the dinosaur bed itself. Qualitative and quantitative analysis of the palynoflora revealed rich and well-preserved non-marine assemblages of pollen and spores, including early angiosperms, and freshwater green algae. Four types of angiosperm pollen are described and assigned to the genus Retimonocolpites Pierce, 1961, but left in open nomenclature. Some marine elements such as dinoflagellate cysts are identified as the result of reworking of Middle and Upper Jurassic sediments. The pollen/spore assemblages depict a vegetational change from principally gymnosperm-dominated assemblages at the base to principally pteridophyte-dominated assemblages at the top of the section. The dinosaur bed shows a pteridophyte-dominated assemblage, with a significantly high amount of the freshwater green alga Scenedesmus novilunaris He Cheng-quan et al., 1992. Samples close to the dinosaur bed yielded the first useful ostracod finds from Smokejacks Brickworks: well-preserved assemblages containing Cypridea clavata (Anderson, 1939), Damonella cf. pygmaea (Anderson, 1941), Stenestroemia cf. cressida Anderson, 1971 and Stenestroemia sp. A, and fragments and damaged valves of a thin-shelled ostracod, possibly belonging to Mantelliana Anderson, 1966. Those identified as Cypridea clavata show a wide range of morphological variety and in opposition to Anderson's (1967, 1985) taxonomic scheme, which would assign them to up to five different taxa, they are considered to be intraspecific variants of a single species. The possibilities and limitations of age determination of the Wealden sediments using palynomorphs and ostracods are discussed; distinct forms of early angiosperm pollen, together with the ostracod fauna, are consistent with an early Barremian age. Pollen and spores are discussed in terms of their parent plants and the reconstruction of vegetation and palaeoclimate. Palynology and ostracods give evidence for temporary freshwater conditions at the time when the Iguanodon died and the carcase was buried.     

Wind wave-forced fine sediment erosion during the slack water periods in Hangzhou Bay,China

The shallow water wave simulation model-SWAN incorporated with a simple fine sediment erosion model is applied to Hangzhou Bay, China, to model the horizontal distribution of the maximum bottom orbital velocity and corresponding fine sediment erosion rates induced by: (1) southeasterly steady winds (5, 20 and 30 m/s), (2) southwesterly steady winds (5 and 20 m/s); (3) northwesterly steady winds (5 and 20 m/s); (4) east-southeasterly steady winds (5 and 20 m/s); (5) easterly steady winds (5 and 20 m/s) under closed and unclosed boundaries; and (6) unsteady winds during the slack water periods. Results suggest: (1) the steady wind wave-induced maximum bottom orbital velocities and corresponding fine sediment erosion rates generally increased with the increasing steady winds; (2) closed and unclosed boundary conditions had more significant influences on modeled fine sediment erosion rates under 5 m/s easterly steady winds than 20 m/s; and (3) steady and unsteady wind wave-induced maximum bottom currents could be significant in eroding fine sediment bed in Hangzhou Bay. The results show implications for geomorphology, sedimentology, coastal erosion, and environmental pollution mitigation in Hangzhou Bay.     

A design methodology for rock slopes susceptible to wedge failure using fracture system modelling

This paper demonstrates how the use of fracture system modelling can be linked to limit equilibrium analysis of rock slopes susceptible to wedge failure. The use of fracture systems highlights some of the limitations inherent in traditional structural data analysis and representation. Consequently it allows for more comprehensive input data that can be used for stability analysis of rock slopes. In particular the developed methodology addresses important issues such as spatial variability and wedge size distributions. The paper introduces a series of guidelines for interpretation of the results of rock slopes. The proposed techniques arguably result in an improved level of confidence in the design of rock slopes susceptible to wedge failure.     

Late Palaeozoic hydrocarbon migration through the Clair field, West of Shetland, UK Atlantic margin

Geochemical analysis of bitumen- and hydrocarbon-bearing fluid inclusions from the Devonian-Carboniferous Clair field indicates that the reservoirs contain a mixture of oils from different marine and lacustrine sources. Reconstruction of the Clair field oil-charge history using fluid inclusion petrography show that oil-charging occurred at times of K-feldspar, quartz and calcite cementation. Temperature–composition–time data yielded from the integration of fluid inclusion microthermometry with high-resolution Ar–Ar dating, date hydrocarbon-bearing K-feldspar overgrowths at 247 ± 3.3 Ma. These data show that in order for oil to be trapped within primary fluid inclusions in K-feldspar overgrowths, hydrocarbon migration throughout the UK Atlantic margin must have been taking place during the Late Palaeozoic and as such, current industry oil-play models based solely on oil charging from Jurassic-Cretaceous marine sources are clearly incomplete and need revision. Apatite fission track analysis and vitrinite reflectance data were used to reconstruct thermal burial histories and assess potential oil generation from Middle Devonian lacustrine source rocks. Thermal history data from wells along The Rona Ridge adjacent to the Clair field show that the Palaeozoic section was heated to greater than 100 °C at some time between 270 and 230 Ma, confirming that Devonian source rocks were mature and expelling oil during the Late Palaeozoic at the time that authigenic K-feldspar overgrowths were growing in the Clair field.